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However, NO x emissions resulting from fossil fuel combustion are estimated at A recent discovery indicated that cosmic ray and solar flares can significantly influence the number of lightning strikes occurring on Earth.

Therefore, space weather can be a major driving force of lightning-produced atmospheric NO x. Agricultural fertilization and the use of nitrogen fixing plants also contribute to atmospheric NO x , by promoting nitrogen fixation by microorganisms.

And the denitrification is basically the reverse process of nitrification. During the denitrification, nitrate is reduced to nitrite then NO then N 2 O and finally nitrogen.

Through these processes, NO x is emitted to the atmosphere. A recent study conducted by the University of California Davis, found that adding nitrogen fertilizer to soil in California is contributing 25 percent or more to state-wide NO x pollution levels.

NO x is a precursor for smog formation which is already a known issue for the state of California.

In addition to contributing to smog, when nitrogen fertilizer is added to the soil and the excess is released in the form of NO, or leached as nitrate this can be a costly process for the farming industry.

A study by the Indiana University determined that forests in the eastern United States can expect to see increases in NO x , as a result to changes in the types of trees which predominate.

Due to human activity and climate change , the maples , sassafras , and tulip poplar are pushing out the beneficial oak , beech , and hickory.

The team determined that the first three tree species, maples, sassafras, and tulip poplar, are associated with ammonia-oxidizing bacteria known to "emit reactive nitrogen from soil.

Nitrogen oxide release from forest soils is expected to be highest in Indiana, Illinois, Michigan, Kentucky and Ohio.

The three primary sources of NO x in combustion processes: [19] [20]. Thermal NO x formation, which is highly temperature dependent, is recognized as the most relevant source when combusting natural gas.

Fuel NO x tends to dominate during the combustion of fuels, such as coal, which have a significant nitrogen content, particularly when burned in combustors designed to minimise thermal NO x.

The contribution of prompt NO x is normally considered negligible. Thermal NO x refers to NO x formed through high temperature oxidation of the diatomic nitrogen found in combustion air.

The three principal reactions the extended Zel'dovich mechanism producing thermal NO x are:. All three reactions are reversible.

Zeldovich was the first to suggest the importance of the first two reactions. The major source of NO x production from nitrogen-bearing fuels such as certain coals and oil, is the conversion of fuel bound nitrogen to NO x during combustion.

Although the complete mechanism is not fully understood, there are two primary pathways of formation. The first involves the oxidation of volatile nitrogen species during the initial stages of combustion.

During the release and before the oxidation of the volatiles, nitrogen reacts to form several intermediaries which are then oxidized into NO.

If the volatiles evolve into a reducing atmosphere, the nitrogen evolved can readily be made to form nitrogen gas, rather than NO x.

The second pathway involves the combustion of nitrogen contained in the char matrix during the combustion of the char portion of the fuels.

This reaction occurs much more slowly than the volatile phase. Nitrogen oxides are released during manufacturing of nitrogen fertilizers.

Though nitrous oxide is emitted during its application, it is then reacted in atmosphere to form nitrogen oxides.

This third source is attributed to the reaction of atmospheric nitrogen, N 2 , with radicals such as C, CH, and CH 2 fragments derived from fuel, [24] rather than thermal or fuel processes.

There is strong evidence that NO x respiratory exposure can trigger and exacerbate existing asthma symptoms, and may even lead to the development of asthma over longer periods of time.

It has also been associated with heart disease, diabetes, birth outcomes, and all-cause mortality, but these nonrespiratory effects are less well-established.

NO x reacts with ammonia , moisture, and other compounds to form nitric acid vapor and related particles.

NO x reacts with volatile organic compounds in the presence of sunlight to form ozone. Ozone can cause adverse effects such as damage to lung tissue and reduction in lung function mostly in susceptible populations children, elderly, asthmatics.

Ozone can be transported by wind currents and cause health impacts far from the original sources. The American Lung Association estimates that nearly 50 percent of United States inhabitants live in counties that are not in ozone compliance.

NO x also readily reacts with common organic chemicals, and even ozone, to form a wide variety of toxic products: nitroarenes , nitrosamines and also the nitrate radical some of which may cause DNA mutations.

Recently another pathway, via NO x , to ozone has been found that predominantly occurs in coastal areas via formation of nitryl chloride when NO x comes into contact with salt mist.

The direct effect of the emission of NO x has positive contribution to the greenhouse effect. Once the concentration of NO x exceeds a certain level, atmospheric reactions result in net ozone formation.

Since tropospheric ozone can absorb infrared radiation, this indirect effect of NO x is intensifying global warming.

There are also other indirect effects of NO x that can either increase or decrease the greenhouse effect.

For instance, ship traffic emits a great amount of NO x which provides a source of NO x over the ocean.

Through this way, the deposition leads to nitrogen fertilization and the subsequent formation of nitrous oxide N 2 O in soil, which is another greenhouse gas.

In conclusion, considering several direct and indirect effects, NO x emissions have a negative contribution to global warming.

NO x in the atmosphere is removed through several pathways. These are ultimately broken down to inorganic nitrate, which is a useful nutrient for plants.

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